Simulating excited-state absorption spectra in upconverting lanthanide doped nanoparticles: KY3F10:Er3+
نویسندگان
چکیده
High-resolution absorption and laser-excited fluorescence studies of KY3F10:Er3+ core-only nanoparticles are presented. A total 49 crystal-field energy levels, distributed amongst 13 multiplets the Er3+ ion, have been deduced for C4v point group symmetry centre in this material. parametrized, single-electron calculation provides an excellent approximation to experimental data with optimized crystal fit parameters that comparable bulk crystal. Simulated spectra, based upon wavefunctions derived from calculations, unequivocally demonstrate excited-state is predominant upconversion mechanism material – agreeing well excitation spectra obtained Yb3+ co-doped samples.
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ژورنال
عنوان ژورنال: Journal of Luminescence
سال: 2022
ISSN: ['1872-7883', '0022-2313']
DOI: https://doi.org/10.1016/j.jlumin.2022.119126